The analogy between a gas-liquid transition and the laminar-jammed transition of traffic was pointed out many times (e.g. (7,17)). The description of traffic in the well-known 2-fluid-model (23) assumes the existence of two phases; and all simulation models which use spatial queues (e.g. (24,26,25)) will display two phases because of the definition of the dynamics. The two phases in models with queues are however much easier to understand than the phases in more realistic models.
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In a gas-liquid transition, one observes the following (see also Fig. 1(a) left):
If a system in the coexistence state is compressed, more droplets form and/or existing ones grow, but the density both inside and outside the droplets remains constant. That is, the system reacts by allocating more space to the high density phase, but not by changing the density either of the gas or the liquid phase. Let us call those two densities and . Eventually, all the space is used up by the liquid. At this point, the system will be homogeneous again and remain so if density is increased further.
The kinetics of the droplet formation (e.g. (27)) is ruled by a balance between surface tension and vapor pressure. Since surface tension pulls the droplet together, it increases the pressure inside the droplet. This interior pressure pushes water molecules out of the droplet. Vapor pressure outside the droplet is the balancing force - it pushes particles into the droplet.
Surface tension and thus interior pressure depend on the droplet radius - the smaller the droplet, the larger the surface tension and thus the interior pressure. The result is that, when coming from small densities, there is a regime, starting at , where large droplets would already be stable, but small droplets are not. That is, if the system were in equilibrium, there would be a coexistence between gas and droplets. But when coming from low density, the homogeneous gaseous phase can survive for some time. This super-critical gas is thus meta-stable. A direct consequence of meta-stability is hysteresis: When coming from low densities, it is possible to go beyond and still remain in the gaseous phase. Only after some waiting time will, by a fluctuation, some particles get close enough to each other to start the formation of a droplet.
When increasing temperature in a gas/liquid system, the 2-phase structure will eventually go away. This happens via and approaching each other and eventually meeting (see Fig. 1(b)). That is, depending on the temperature , a fluid system will either display transitions from gas to coexistence and from coexistence to liquid, or there will be no transition at all.
We will now move on to describe the supporting evidence for our claims. As is typical in computational science, our evidence is based on computer simulations. It is however backed up by generic knowledge about phase transitions as they are well understood in physics.